The stereochemical course of sulphuryl transfer catalysed by arylsulphatase II from Aspergillus oryzae.
نویسندگان
چکیده
Phenyl [(R)-16O,17O,18O]sulphate was synthesized and used to study the stereochemical course of sulphuryl transfer to p-cresol catalysed by arylsulphatase II from Aspergillus oryzae. The reaction was shown to proceed with retention of configuration at the sulphur atom, providing evidence for the involvement of a sulpho-enzyme intermediate on the reaction pathway.
منابع مشابه
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ورودعنوان ژورنال:
- The Biochemical journal
دوره 287 ( Pt 3) شماره
صفحات -
تاریخ انتشار 1992